• 0 Posts
  • 16 Comments
Joined 8 months ago
cake
Cake day: March 31st, 2025

help-circle

  • i don’t mean beta-oxidation, it’s just a series of separated normal reactions. i mean something like this: when first learning about ketones, you might learn about aldol condensation, which has enol as a nucleophile and another carbonyl as electrophile. at some other point you might learn about strecker reaction, which has iminium ion as electrophile and cyanide as nucleophile. but really, what you can do is mix and match, and you can pair enolizable ketone and iminium (mannich reaction) or carbonyl and cyanide (cyanohydrin formation) and then generalize, for example you don’t need strictly ketone for mannich, you can use any electron rich conjugated system like malonate or nitroalkane anion (henry reaction) or phenol or indole. to figure this out you need to study mechanisms. these last two are usually treated as variants of friedel-crafts reaction, but really categories like this are fake

    and to get that right, you need to know how these reactive intermediates look like, how reactive they are, what influences their stability which means that ochem starts with discussion of carbocations, carboanions, radicals, their shapes and orbitals involved, hyperconjugation, solvent effects and the like. and then first reactions taught are sn1/sn2, because these showcase these fundamentals nicely, and from there, it’s about introduction of more compound classes

    we only had synthons introduced during lecture at around 4th year, and only for ochem path, it’s not doing a lot at that point and imo would have much more impact right after ochem intro course














  • sounds like it’s not supposed to be a general use tool, but instead for counterintelligence only:

    The Ministry of the Interior anticipates submitting around 30 requests per year for the surveillance of unencrypted messages and between 5 to 15 requests for encrypted communications. If there are 30 instances of encrypted message monitoring within a single calendar year, the Interior Minister is obligated to inform a permanent subcommittee of the National Council, which is the directly elected chamber of the Austrian Parliament.

    Each surveillance method will require case-by-case approval from the Federal Administrative Court. The process involves a legal protection officer from the Ministry of the Interior, who will have three business days to respond to any request. Following that, a panel of three judges from the Federal Administrative Court will review the case. In urgent situations, an individual judge may grant approval, supported by a 24-hour judicial service system.

    https://themunicheye.com/austrian-government-approves-malware-surveillance-23431

    broad use would expose its existence and make any 0days useless in short order